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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes : A Study of Molecular and Electronic Structure / by Carola S. Vogel
(Springer Theses, Recognizing Outstanding Ph.D. Research. ISSN:21905053)

データ種別 電子ブック
著者標目 *Vogel, Carola S author
SpringerLink (Online service)
出版者 (Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer)
出版年 2012

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URL 図書館共通

EB007060
9783642272547 禁帯出

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巻次 ISBN:9783642272547
大きさ XVIII, 132 p. 98 illus., 66 illus. in color : online resource
一般注記 Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts
HTTP:URL=https://doi.org/10.1007/978-3-642-27254-7
件 名 LCSH:Chemistry, inorganic
LCSH:Catalysis
LCSH:Enzymes
FREE:Inorganic Chemistry
FREE:Catalysis
FREE:Enzymology
分 類 LCC:QD146-197
DC23:546
書誌ID OB00007060
ISBN 9783642272547

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