Mendeley出力
Two Studies in Gas-Phase Ion Spectroscopy : Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics / by Matthew J. Simpson
(Springer Theses, Recognizing Outstanding Ph.D. Research. ISSN:21905053)
| データ種別 | 電子ブック |
|---|---|
| 著者標目 | *Simpson, Matthew J author SpringerLink (Online service) |
| 出版者 | (Berlin, Heidelberg : Springer Berlin Heidelberg) |
| 出版年 | 2012 |
書誌詳細を非表示
| 巻次 | ISBN:9783642231292 |
|---|---|
| 大きさ | XIV, 162 p : online resource |
| 一般注記 | Introduction and background information -- The experiments.- Vacuum-ultraviolet negative photoion spectroscopy of SF6, CF4 and SF5CF3 -- Vacuum-ultraviolet negative photoion spectroscopy of CF3Cl, CF3Br and CF3I -- Vacuum-ultraviolet negative photoion spectroscopy of SF5Cl -- Vacuum-ultraviolet negative photoion spectroscopy of small polyatomic molecules -- The reactions of CFn+ (n = 1-3) with C2H4, C2H3F, CH2CF2 and C2HF3 -- The reactions of C2F4+ with C2H4, C2H3F, CH2CF2 and C2HF3 -- Reactions of OH-, O-, CF3-, F- and O2- with C2H4, C2H3F, CH2CF2, C2HF3 and C2F4 In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules. The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals HTTP:URL=https://doi.org/10.1007/978-3-642-23129-2 |
| 件 名 | LCSH:Spectroscopy LCSH:Chemistry, Physical organic FREE:Spectroscopy/Spectrometry FREE:Spectroscopy and Microscopy FREE:Physical Chemistry |
| 分 類 | LCC:QD95-96 DC23:543.2-543.8 |
| 書誌ID | OB00007208 |
| ISBN | 9783642231292 |