Mendeley出力
Late Transition Metal-Carboryne Complexes : Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes / by Zaozao Qiu
(Springer Theses, Recognizing Outstanding Ph.D. Research. ISSN:21905053)
| データ種別 | 電子ブック |
|---|---|
| 著者標目 | *Qiu, Zaozao author SpringerLink (Online service) |
| 出版者 | (Berlin, Heidelberg : Springer Berlin Heidelberg) |
| 出版年 | 2012 |
書誌詳細を非表示
| 巻次 | ISBN:9783642243615 |
|---|---|
| 大きさ | XVIII, 134 p : online resource |
| 一般注記 | Introduction -- Nickel-1,2-o-Carboryne Complexes -- Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes -- Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes -- Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes -- Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes -- Conclusion -- Experimental Section In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molecules in a single operation from very simple precursors. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and until now limited efficient synthetic methods to obtain functional carborane materials have restricted their application. This work breaks new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry. HTTP:URL=https://doi.org/10.1007/978-3-642-24361-5 |
| 件 名 | LCSH:Chemistry, Organic LCSH:Chemistry, inorganic LCSH:Biochemistry FREE:Organic Chemistry FREE:Inorganic Chemistry FREE:Medicinal Chemistry |
| 分 類 | LCC:QD415-436 DC23:547 |
| 書誌ID | OB00007166 |
| ISBN | 9783642243615 |