Nanostructured polymer blends / editors: Sabu Thomas, Robert Shanks, Sarathchandran Chandrasekharakurup
(Micro and Nano Technologies)
データ種別 | 電子ブック |
---|---|
著者標目 | Thomas, Sabu Shanks, Robert Sarathchandran, C. |
出版者 | Waltham, MA : William Andrew |
出版年 | 2014 |
書誌詳細を非表示
巻次 | electronic bk. ; ISBN:9781455731602 electronic bk. ; ISBN:1455731609 XISBN:9781455731596 |
---|---|
大きさ | 1 online resource (570 p.) |
内容注記 | Machine generated contents note: ch. 1 Polymer Blends 1.1.Introduction 1.2.Polymer Polymer Miscibility Theory 1.2.1.Macromolecular Solubility 1.2.2.Binodal Phase Separation 1.2.3.Spinodal Phase Separation 1.2.4.Nanophase Separation 1.2.5.Blends of Semicrystalline Polymers 1.3.Incompatible Polymer Blends 1.4.Miscible Polymer Blends 1.4.1.Interactions and Miscibility 1.4.2.Loss of Desirable Properties 1.5.Cross-Linking of Miscible Polymer Blends 1.5.1.Cross-Linking of the Major Phase 1.5.2.Cross-Linking of the Minor Phase 1.6.Compatible Polymer Blends 1.6.1.Compatible Polymers 1.6.2.Shear-Induced Colloid Formation 1.7.Nanophase Blends 1.7.1.Properties of Nanoblends 1.8.Conclusion References ch. 2 Characterization of Nanostructured Materials 2.1.Introduction 2.2.Microscopies 2.2.1.Light Scattering and Microscopy 2.3.Laser Scanning Confocal Microscopy 2.3.1.Ultraviolet Confocal Microscopy 2.3.2.Raman Microscopy 2.4.Optical Ultramicroscopy 2.5.Transmission Electron Microscopy 2.5.1.Scanning Transmission Electron Microscopy 2.6.Scanning Electron Microscopy 2.7.Atomic Force Microscopy 2.8.Image Analysis 2.9.Molecular Modeling 2.10.Small Angle X-ray Scattering 2.11.Wide Angle X-ray Scattering 2.12.X-Ray Tomography 2.13.Nuclear Magnetic Resonance 2.13.1.NMR Relaxation Times 2.14.Surface Area Analysis 2.15.Indirect Methods that do not Allow Visualization 2.16.Conclusion References ch. 3 Theoretical Modeling of Nanostructured Formation in Polymer Blends 3.1.Introduction 3.2.The Freely Jointed Chain 3.3.Solubility and Interaction Parameters in Nanostructured Polymer Blends 3.3.1.Thermodynamics of a Polymer Solution 3.3.2.Flory Krigbaum and Modified Flory Huggins Theory 3.3.3.Phase Equilibrium 3.4.Prediction of Mechanical, Electrical, and Thermal Properties of Semicrystalline Polymer and Nanostructured Polymer Blends 3.4.1.Polymer Properties 3.4.2.Diffusion and Solubility Properties 3.4.3.Electrical Properties 3.4.4.Thermal Properties 3.4.5.Mechanical Properties 3.5.Modeling of Polymers in Solution and the Morphological Control of Nanostructured Polymer Blends 3.5.1.The Thermodynamic Model 3.5.2.The Kinetic Model 3.5.3.The Navier Stokes Equation 3.5.4.The Level Set Method 3.5.5.The Phase Field Method 3.6.Multiscale Modeling for Nanostructured Polymer Blend Material Design 3.6.1.Molecular Dynamic Simulation 3.6.2.Monte Carlo (MC) Simulations 3.6.3.Molecular Mechanics (MM) 3.7.Volume Fraction Modules for Nanostructured Polymer Blends 3.8.Recent Advances 3.9.Conclusion 3.10.Recommendations References Further Reading ch. 4 Compatibilization as a Tool for Nanostructure Formation 4.1.Introduction 4.2.Theoretical Background of Compatibilization of Polymer Blends 4.2.1.A Brief Review of Available Compatibilization Technologies 4.3.Types of Polymer Blend Compatibilization 4.3.1.Addition Compatibilization 4.3.2.Reactive Compatibilization 4.4.Types of Compatibilizers Suitable for Different Polymer Pairs 4.4.1.Price versus Performance 4.4.2.Processing Conditions that Usually Induce (Metastable) Morphologies 4.5.Morphology Property Consideration 4.6.Use of Nanofiller as a Compatibilizer for Immiscible Polymer Blends 4.7.Recent Advances in Compatibilized Nanostructured Polymer Blends 4.8.Thermodynamic Considerations of Polymer Blends 4.9.Morphology Evolution of a Polymer Blend 4.10.Compatibilized Nanostructured Polymer Blends 4.10.1.Solid-State Shear Pulverization (SSSP) 4.11.Applications of Compatibilized Nanostructured Polymer Blends 4.12.Conclusion 4.13.Recommendations References ch. 5 Nanofilled Thermoplastic Thermoplastic Polymer Blends 5.1.Introduction 5.1.1.General Aspects of Nanofilled Polymer Blends 5.2.Interactions in Nanofilled Thermoplastic Polymer Blends 5.3.Kinetic Effects on the Morphology of Nanofilled Thermoplastic Polymer Blends 5.3.1.Mixing Procedures 5.3.2.Viscosity 5.3.3.Mechanisms of Nanoparticle Migration 5.4.Compatibilizing Effect of Nanoparticles in Thermoplastic Polymer Blends 5.4.1.Morphology Changes 5.4.2.Mechanisms of Compatibilization 5.4.3.Stability of the Morphology 5.5.Mechanical Properties 5.6.Conclusion References ch. 6 Nanostructure Formation in Thermoset/Block Copolymer and Thermoset/Hyperbranched Polymer Blends 6.1.Introduction 6.2.Nanostructure Formation in Thermoset/Block Copolymer Blends 6.2.1.Microphase Separation Mechanism 6.2.2.Preparation Methods of the Block Copolymer Modified Epoxy Thermoset 6.2.3.Morphology of the Block Copolymer Modified Epoxy and its Controlling Parameters 6.3.Microstructure Formation in Thermoset/Hyperbranched Polymer Blends 6.3.1.Thermodynamics and Kinetics of the Microphase Separation 6.3.2.Time-Temperature-Transformation (TTT) Diagram of the Hyperbranched Polymer Modified Epoxy Thermoset and Preparation 6.3.3.Morphology of the Hyperbranched Polymer Modified Epoxy and its Controlling Parameters 6.4.Mechanical and Thermal Properties 6.4.1.Fracture Toughness 6.4.2.Glass Transition Temperature |
一般注記 | Includes index Includes bibliographical references and index Over 30% of commercial polymers are blends or alloys or one kind or another. Nanostructured blends offer the scientist or plastics engineer a new range of possibilities with characteristics including thermodynamic stablility; the potential to improve material transparency, creep and solvent resistance; the potential to simultaneously increase tensile strength and ductility; superior rheological properties; and relatively low cost. Nanostructured Polymer Blends opens up immense structural possibilities via chemical and mechanical modifications that generate novel properties and |
件 名 | FREE:Nanostructured materials FREE:Polymeric composites -- Industrial applications 全ての件名で検索 FREE:Polymeric composites FREE:Polymers LCSH:Polymeric composites -- Microstructure 全ての件名で検索 LCSH:Polymeric composites -- Industrial applications 全ての件名で検索 LCSH:Nanostructured materials FREE:TECHNOLOGY & ENGINEERING / Engineering (General) FREE:TECHNOLOGY & ENGINEERING / Reference FREE:Electronic books LCSH:Electronic books |
分 類 | DC:620.1 |
書誌ID | OB00006670 |
ISBN | 9781455731602 |
NCID | LB40010885 |