Mendeley出力
The synthetic organic chemist's companion / Michael C. Pirrung
| データ種別 | 電子ブック |
|---|---|
| 著者標目 | *Pirrung, Michael C. NetLibrary, Inc |
| 出版情報 | Hoboken, N.J. : Wiley-Interscience , c2007 |
書誌詳細を非表示
| 巻次 | electronic bk. ; ISBN:9780470141038 electronic bk. ; ISBN:0470141034 |
|---|---|
| 大きさ | xiii, 198 p. : ill. (some col.) ; 23 cm |
| 本文言語 | 英語 |
| 内容注記 | Searching the literature. Commercial availability ; Literature preparations Reagents. Short path distillation ; Ampules ; Reagent solutions ; Titration ; Reagent storage ; Subtle reagent variations ; Dangerous reagents ; Reagent properties Gases. Lecture bottles ; Tanks or cylinders ; Gas safety Reactions on a small scale - 1-25 mmol. Reaction flasks ; Stirring ; Glass joints ; Inert atmosphere ; Apparatus for addition ; Condensers ; Other equipment and considerations Temperature control. Heating ; Cooling Solvents. Selection ; Purity ; Degassing ; Ammonia The research notebook Conducting the reaction itself. Reagents supplied as dispersions ; Azeotropic drying ; Stoichiometry ; Syringe and inert atmosphere techniques ; General procedure for transfer of materials by syringe ; Addition ; Special techniques: Water removal, Reactions above atmospheric pressure, Reagent gases, Ultrasonication ; Quenching ; Specialized reagents: Diazomethane, Lithium aluminum hydride, Hydrogen peroxide ; Reaction time vs. purification time Following the reaction. Thin layer chromatography (TLC): Cutting glass TLC plates, Spotting TLC plates, Eluting TLC plates, Visualizing TLC plates ; Gas chromatography (GC) ; High pressure liquid chromatography (HPLC) ; NMR spectroscopy Working up reactions. Solvent extraction ; Drying organic solutions ; Specialized work-ups: Reactions producing triphenylphosphine oxide, Reactions involving boron compounds, Reactions involving copper salts, Reactions involving aluminum reagents, Reactions involving tin reagents Evaporation Vacuum systems. Vacuum sources ; Vacuum manifolds ; Vacuum gauges Purification of products. Distillation ; Silica gel chromatography ; Flash column chromatography ; Gradients ; Special absorbents: Triethylamine-treated silica gel, Oxalic acid-coated silica gel, Silver nitrate-impregnated silica gel, Other sorbents ; Preparative gas chromatography Methods for structure elucidation. Nuclear magnetic resonance spectroscopy (NMR) ; Infrared spectroscopy (IR) ; Ultraviolet spectroscopy (UV) ; Combustion analysis ; Mass spectrometry ; Crystallography Cleaning up after the reaction Specific examples. The experimental ; The Org. Syn. Prep ; Comparison Strategies for reaction organization Appendices. 1. NMR spectral data of common contaminants of organic reaction products ; 2. Synthetic solvent selection chart ; 3. Recipes for TLC stains ; 4. Mixotropic series ; 5. Stuck joints ; 6. Acidities of organic functional groups ; 7. Acidities of organic functional groups in DMSO ; 8. Web resources for synthetic chemistry |
| 一般注記 | Includes bibliographical references (p. 187-188) and index Electronic reproduction. Boulder, Colo. : NetLibrary, 2007. Available via World Wide Web. Access may be limited to NetLibrary affiliated libraries |
| 件 名 | LCSH:Organic compounds -- Synthesis
全ての件名で検索
FREE:Electronic books |
| 分 類 | DC22:547/.2 |
| 書誌ID | OB00000506 |
| ISBN | 9780470141038 |
| NCID | LB40000296 |